Journal
ORGANOMETALLICS
Volume 29, Issue 1, Pages 257-262Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900889k
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- National Science Foundation
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This paper describes an efficient synthesis of the cationic platinum complex [(N-CH3-bpym)PtCl2](+) (N-CH3-bpym = N-methylbipyrimidinium) and evaluation of its catalytic activity in H/D exchange reactions of CH4 (with D2SO4) and benzene (with CF3CO2D). With both substrates (N-CH3-bpym) PtCl2](+) shows C-H activation reactivity comparable to that of its neutral analogue (bpym)PtCl2 (bpym = bipyrimidine). The origin of this similar reactivity is proposed to be the in situ formation of the same active catalyst in both cases.
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