Journal
ORGANOMETALLICS
Volume 29, Issue 7, Pages 1865-1868Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om1000937
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- Ministere de l'Enseignement Superieur et de la Recherche
- CNRS
- Institut Universitaire de France
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Methyl abstraction from a neutral aluminum complex stabilized by a salen-like fluorinated dialkoxide-diimino ligand yields the corresponding cationic species, which exists as alive-coordinate Et2O adduct in the solid state and in solution. This complex promotes the cationic polymerization of propylene oxide and p-methylstyrene at low temperatures.
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