Journal
ORGANOMETALLICS
Volume 29, Issue 7, Pages 1530-1533Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100061q
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- Ministere de la Recherche et de la Technologic
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In the presence of [Cl(C3H5)Pd](2), diphenylphosphinoazomethinylate salt (DIPPA M) la forms an original chiral eta(1)-allyl palladium complex, 2. Precatalyst 2/MgBr2 is an efficient catalyst for asymmetric allylic alkylation, giving good yields and ee's in the reactions of rac-4-acetoxy-2-pentene or rac-3-acetoxy-1,3-diphenyl-1-propene and dimethyl malonate (respectively 77% and 96% yield; 66% and 96% ee). Preliminary mechanistic studies have highlighted the key role of the eta(1)-coordination mode of the ally, fragment.
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