Journal
ORGANOMETALLICS
Volume 29, Issue 17, Pages 3765-3768Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100262x
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Funding
- NIH [F32GM078734, K99GM084302, 5RO1GM31332]
- National Science Foundation
- DoD, Air Force Office of Scientific Research, National Defense Science and Engineering Graduate (NDSEG) [32 CFR 168a]
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New procedures for the synthesis of N-heterocyclic carbenes with multiple fused rings have been developed utilizing a key ring-closing metathesis step. Rhodium complexes were obtained via the pentafluorophenyl carbene adducts. Solid-state structural behaviors of the new carbene ligands were analyzed via X-ray crystallography.
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