Journal
ORGANOMETALLICS
Volume 29, Issue 21, Pages 5230-5235Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100365t
Keywords
-
Categories
Funding
- National Science Foundation [CHE-0906179, CHE-0840504]
- Robert A. Welch Foundation [N-1322]
- Alexander von Humboldt Foundation
- NIU Inaugural Board of Trustees
Ask authors/readers for more resources
The synthesis and thermal properties of phenylene and triazine core based symmetrical macromolecules containing three to six cobaltabis(dicarbollide) clusters are reported. The zwitterionic oxonium derivative of cobaltabis(dicarbollide), [3,3'-Co(8-C4H8O2-1,2-C2B9H10)(1',2'-C2B9H11)], has been used for the synthetic transformations, and silicon tetrachloride and triflic acid were used as the cyclotrimerization reagents. Compounds containing multiple cobaltabis(dicarbollide) clusters are found to be extremely thermally stable, and only a 10-30% mass loss occurred up to 700 degrees C.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available