Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3(CO)10(dppm) to HOs3(CO)8[μ-PhP(C6H4-μ2,η1)CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C−H and π-Aryl Intermediates at an Intact Triosmium Cluster

Published 2010 View Full Article

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Title
Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3(CO)10(dppm) to HOs3(CO)8[μ-PhP(C6H4-μ2,η1)CH2PPh2]: Experimental and DFT Evidence for the Participation of Agostic C−H and π-Aryl Intermediates at an Intact Triosmium Cluster
Authors
Keywords
-
Journal
ORGANOMETALLICS
Volume 29, Issue 18, Pages 4041-4057
Publisher
American Chemical Society (ACS)
Online
2010-09-01
DOI
10.1021/om100475v

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