Journal
ORGANOMETALLICS
Volume 28, Issue 15, Pages 4613-4616Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900285e
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- Sasol Technology (Pty) Ltd
- Univeristy of Bristol
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Ligand backbone alkylation of the complex [Cr(CO)(4)dppnt)] (dppm = bis(disphenylphosphino)methane) with alkyl iodides yields the C-substituted dppm ligand complexes [Cr(CO)(4){Ph2PCH(R)PPh2}] (R = methyl, n-hexyl, benzyl). Activation of these complexes via one-electron oxidation with Ag[(Al(OC4F9)(4)] and CO removal with triethylaluminium, or (in the cas of R = methyl) by in situ treatment of the free ligand with a chromium salt and modified methyl alumoxane (MMAO), leads to catalysts showing some selectivity for ethylene trimerization and tetramerization. NMR spectroscopic studies of the parent dppm or [Cr(CO)(4)(dppm)] compounds suggest that ligand deprotonation and decomplexation may be the cause of the surprisingly poor catalytic performance of these specific derivatives.
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