Review
Chemistry, Inorganic & Nuclear
Matthew T. Whited
Summary: This Perspective summarizes the common modes of cooperativity demonstrated for pincer frameworks featuring metal/main-group bonds, highlighting similarities among boron, aluminium, and silicon donors and identifying directions for further development.
DALTON TRANSACTIONS
(2021)
Article
Chemistry, Inorganic & Nuclear
Kai Li, Jialu He, Yue Zhao, Congqing Zhu
Summary: A new monoanionic nitrogen-phosphorus ligand was designed and used to synthesize several uranium complexes. The reactivity of these complexes was investigated, and it was found that the ligand is an effective platform for the construction of species with uranium-metal bonds.
INORGANIC CHEMISTRY FRONTIERS
(2023)
Article
Chemistry, Inorganic & Nuclear
Samuel M. M. Bhutto, Brandon Q. Q. Mercado, Patrick L. L. Holland
Summary: In this study, the capability of iron(I) alkynyl complexes to bind N-2 was explored and a crystal structure of an iron(I) alkynyl complex with N-2 was obtained. It was further demonstrated that the alkynyl ligand is resistant to migration possibly due to the high Fe-C bond energy.
INORGANIC CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
J. L. S. Milani, A. F. P. Biajoli, F. I. Batista, R. S. Oliboni, O. L. Casagrande
Summary: A series of new Cr(III) complexes were successfully synthesized and showed moderate activity in ethylene oligomerization, with a uniform distribution of oligomers and polymer production ranging from 1.2% to 9.8%. The catalytic activity is mainly controlled by electronic effects at the thioether/imine groups.
NEW JOURNAL OF CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Selena L. Staun, Guang Wu, Wayne W. Lukens, Trevor W. Hayton
Summary: In this study, two mixed-actinide nitride complexes were successfully synthesized and further characterized using various analytical methods, providing important data support for a deeper understanding of the properties and structures of mixed-metal nitride complexes.
Article
Chemistry, Inorganic & Nuclear
Akira Okumura, Priyabrata Ghana, Fabian Fink, Regina Schmidt, Alexander Hoffmann, Thomas P. Spaniol, Sonja Herres-Pawlis, Jun Okuda
Summary: This study describes titanium(III) and titanium(IV) formate complexes supported by a stericay encumbering tris(phenolato) amine ligand. The authors synthesized various titanium complexes with different coordination numbers and oxidation states through different chemical reactions, and fully characterized them using various analytical methods.
DALTON TRANSACTIONS
(2022)
Article
Chemistry, Multidisciplinary
Vikramjeet Singh, Abhishek Kundu, Kirti Singh, Debashis Adhikari
Summary: Formazan ligands have long been investigated as redox-noninnocent backbones, but their catalytic efficiency governed by redox noninnocence remains elusive. In this study, we report an iron-formazanate molecule that can efficiently prepare alpha-keto amides through a tightly regulated reductive cleavage of the substrate molecule by the electron donation from the formazanate, in a reversible manner.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Inorganic & Nuclear
Hui Guo, Dongjing Hong, Peng Cui
Summary: Tripodal tris(siloxide) ligand supported rare-earth metal complexes LLn(iii) (Ln = Ce, Pr, Tb, Y, Lu) were synthesized. The Ce(iii) complex was oxidized to Ce(iv) chloride complex and then reacted with tBuONa to form a Ce(iv) tert-butoxide complex, both of which showed substantial stability.
DALTON TRANSACTIONS
(2023)
Article
Chemistry, Inorganic & Nuclear
Ricardo A. Peralta, Michael T. Huxley, Jorge Albalad, Christopher J. Sumby, Christian J. Doonan
Summary: MOFs offer a unique matrix for isolating and stabilizing specific transition-metal complexes, and an in situ anion metathesis strategy facilitates the post-synthetic modification of Cu(I) complexes appended to MOFs. By exchanging coordinated chloride for weakly coordinating anions in the presence of CO or ethylene, labile MOF-appended Cu(I) complexes featuring CO or ethylene ligands are prepared and structurally characterized. This allows small and moderately sized molecules to access the isolated Cu(I) sites, displacing the place-holder CO ligand, mimicking ligand-exchange processes in Cu-centered catalysis.
INORGANIC CHEMISTRY
(2021)
Review
Chemistry, Inorganic & Nuclear
Takashi Komuro, Yumiko Nakajima, Jun Takaya, Hisako Hashimoto
Summary: This review summarizes recent progress in the chemistry of transition metal complexes supported by multidentate chelate ligands, focusing on the incorporation of electropositive Group 13 and Group 14 elements as coordinating atoms. These electropositive element-based ligands offer unique functionalities and have applications in catalysis.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Multidisciplinary
Erlin Yue, Lea Dettling, Julian A. W. Sklorz, Selina Kaiser, Manuela Weber, Christian Mueller
Summary: The novel tosyl- and mesitylsulfonyl-substituted triazaphospholes were synthesized and characterized. The results presented here provide a new strategy for selectively preparing such coordination compounds in a one-pot approach.
CHEMICAL COMMUNICATIONS
(2021)
Article
Chemistry, Multidisciplinary
D. M. Ramitha Y. P. Rupasinghe, Makayla R. Baxter, Himanshu Gupta, Andrew T. Poore, Robert F. Higgins, Matthias Zeller, Shiliang Tian, Eric J. Schelter, Suzanne C. Bart
Summary: This study presents the first synthesis of a non-uranyl, f-element oxo complex from dioxygen in dry air. The characterization of the complexes using various spectroscopic techniques confirmed their electronic structures.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Yubin M. Kwon, Yuri Lee, Anna K. Schmautz, Timothy A. Jackson, Dong Wang
Summary: The recent focus on developing high-valent non-oxo-metal complexes has proven effective in studying their rich chemistry. In this study, a formal mononuclear Ni(IV)-nitrate complex was obtained and its geometric and electronic structures, bonding interactions, and spectroscopic properties were analyzed.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Fanji Kong, Pablo Rios, Conner Hauck, Francisco Jose Fernandez-de-Cordova, Diane A. Dickie, Laurel G. Habgood, Amor Rodriguez, T. Brent Gunnoe
Summary: We have demonstrated the dimerization and oligomerization reactions of ethylene using bis(phosphino)boryl supported Ni(II) complexes as catalyst precursors. The addition of alkylaluminum(III) compounds or other Lewis acid additives enhances the activity and selectivity of these Ni(II) complexes, leading to the production of butenes and higher olefins. Our studies suggest that this catalysis involves a cooperative activation of ethylene by the Ni-B unit, resulting in the formation of a key borametallacycle intermediate.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Physical
Neda Arabzadeh Nosratabad, Zhicheng Jin, Liang Du, Mannat Thakur, Hedi Mattoussi
Summary: In this study, we found that N-heterocyclic carbenes (NHCs) can rapidly coordinate onto colloidal gold nanoparticles (AuNPs), with multidentate NHC polymer coating showing the highest affinity to AuNPs and exhibiting long-term colloidal stability and better resistance to competition from reducing molecules. These findings provide additional insights into the interaction and coordination of NHC molecules with Au surfaces.
CHEMISTRY OF MATERIALS
(2021)
Review
Chemistry, Analytical
Mark D. Straub, John Arnold, Julianna Fessenden, Jaqueline L. Kiplinger
ANALYTICAL CHEMISTRY
(2021)
Article
Chemistry, Organic
Agnieszka Nowak-Krol, Beata Koszarna, Maciej Krzeszewski, Trevor D. Lohrey, John Arnold, Daniel T. Gryko
Article
Chemistry, Physical
Eduardo Martinez-Gonzalez, Humberto G. Laguna, Mariano Sanchez-Castellanos, Sergio S. Rozenel, Victor M. Ugalde-Saldivar, Carlos Amador-Bedolla
ACS APPLIED ENERGY MATERIALS
(2020)
Article
Chemistry, Inorganic & Nuclear
Brighton A. Skeel, Michael A. Boreen, Trevor D. Lohrey, John Arnold
INORGANIC CHEMISTRY
(2020)
Article
Chemistry, Physical
Martha M. Flores-Leonar, Carlos R. Azpilcueta, Carlos Amador-Bedolla, Sergio S. Rozenel
Summary: The study focused on alkene photoisomerization reactions using experimental data and computational calculations. Results showed that the trans-species can be converted to the cis-isomer with a high conversion rate due to energy transfer mechanism. This highlights the importance of understanding the energy requirements of the photocatalyst in isomerization reactions.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2021)
Article
Chemistry, Inorganic & Nuclear
Jade Fostvedt, Michael A. Boreen, Robert G. Bergman, John Arnold
Summary: This study demonstrates the formation of a diverse array of organic and organometallic products containing newly formed C-C bonds via successive methyl transfers from di-, tri-, and tetramethyl Ta(V) precursors to unsaturated small molecule substrates. The reactions of Ta(V) methyl complexes with CO led to the formation of oxo enolate Ta(V) products and imido enamine Ta(V) products. Surprisingly, a new dianionic scorpionate ligand was formed through a reaction involving methyl transfer from the metal center. Mechanistic studies revealed a new reaction pathway in early transition metal chemistry.
INORGANIC CHEMISTRY
(2021)
Review
Chemistry, Multidisciplinary
Erik T. Ouellette, Julian S. Magdalenski, Robert G. Bergman, John Arnold
Summary: Low-valent transition metalates are highly reactive chemical reagents that find applications in organic synthesis, small-molecule activation, transient species stabilization, and M-E bond formation. Recent studies have discovered new types of highly reactive metalates without traditional carbonyl ligands. These metalates display unique reactivity in small-molecule activation, metal-metal bond formation, and heterometallic complex synthesis.
ACCOUNTS OF CHEMICAL RESEARCH
(2022)
Article
Chemistry, Inorganic & Nuclear
Anukta Jain, Jade Fostvedt, Benjamin M. Kriegel, David W. Small, Lauren N. Grant, Robert G. Bergman, John Arnold
Summary: In this study, the reactivity between a beta-diketiminate-supported niobium(III) imido complex and alkyl azides was demonstrated, resulting in the formation of niobatetrazene complexes. The reaction mechanism was also determined using computational methods.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Michael A. Boreen, Christopher Z. Ye, Andrew Kerridge, Karl N. McCabe, Brighton A. Skeel, Laurent Maron, John Arnold
Summary: This study investigates the mechanism of isomerization of uranium complexes. Experimental and computational studies reveal two different intramolecular C-H activation mechanisms involved.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Inorganic & Nuclear
Erik T. Ouellette, Julian S. Magdalenski, Robert G. Bergman, John Arnold
Summary: We report the synthesis and characterization of a novel rhenium-group 9 heterobimetallic diazenido species and its related diazenido and hydride complexes. Furthermore, we demonstrate the possibility of N-C bond formation in heterobimetallic complexes and investigate their properties using spectroscopy and computational studies.
INORGANIC CHEMISTRY
(2022)
Article
Chemistry, Multidisciplinary
Christopher Z. Ye, Iker Del Rosal, Michael A. Boreen, Erik T. Ouellette, Dominic R. Russo, Laurent Maron, John Arnold, Clement Camp
Summary: Reaction of potassium pentamethylcyclopentadienyl iridate tris-hydride with UCl4 and ThCl4 led to the generation of multimetallic complexes with different hydride bonding modes. Computational studies suggest that the bonding between U/Th and Ir is significant and involving f-orbitals. The variation in hydride bonding is attributed to differences in dispersion effects.
Review
Chemistry, Multidisciplinary
Gabriela I. Vargas-Zuniga, Michael A. Boreen, Daniel N. Mangel, John Arnold, Jonathan L. Sessler
Summary: The diverse coordination modes and electronic features of actinide complexes of porphyrins and related oligopyrrolic systems have been the subject of interest since the 1960s. Most work has focused on thorium and uranium, but the ligand environments provided by porphyrinoids have led to the stabilization of unique complexes with early actinides. This review summarizes key examples of prophyrinoid actinide complexes, with emphasis on synthesis, structure, electronic features, and reactivity patterns of representative systems.
CHEMICAL SOCIETY REVIEWS
(2022)
Article
Chemistry, Inorganic & Nuclear
Erik T. Ouellette, Ambre Carpentier, I. Joseph Brackbill, Trevor D. Lohrey, Iskander Douair, Laurent Maron, Robert G. Bergman, John Arnold
Summary: Salt metathesis reactions between a low-valent rhenium(I) complex and a series of amidinate-supported tetrylenes led to the formation of rhenium metallotetrylenes with varying extents of Re-E multiple bonding. Temperature played a crucial role in the reactions, leading to isolation of unusual products under different conditions, reflecting the complexity of these metal complexes. Bonding interactions within these complexes were discussed through various spectroscopic, structural, and computational investigations.
DALTON TRANSACTIONS
(2021)
Review
Chemistry, Inorganic & Nuclear
Michael A. Boreen, John Arnold
DALTON TRANSACTIONS
(2020)
Article
Chemistry, Multidisciplinary
Jade Fostvedt, Lauren N. Grant, Benjamin M. Kriegel, Andreas H. Obenhuber, Trevor D. Lohrey, Robert G. Bergman, John Arnold