4.5 Article

Formation of a Novel P,C-Cage Ligand via a P-C5Me5-Substituted Li/Cl Phosphinidenoid Complex

Journal

ORGANOMETALLICS
Volume 28, Issue 16, Pages 4636-4638

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om900331g

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Funding

  1. DFG [STR 411/26-1]
  2. COST [CM0802]

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The novel P,C-cage ligand in the dinuclear tungsten complex 3 was obtained by reaction of the Li/Cl phosphinidenoid complex 2, characterized by, NMR spectroscopy, at low, temperature; complex 3 was characterized by elemental analysis and NMR, IR, and MS studies and by single-crystal X-ray diffraction.

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