4.5 Article

A 14-VE Platinum(0) Phosphabarrelene Complex in the Hydrosilylation of Alkynes

Journal

ORGANOMETALLICS
Volume 28, Issue 8, Pages 2360-2362

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om900067f

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Funding

  1. CNRS (Centre National de la Recherche Scientifique)
  2. Ecole Polytechnique

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A bulky phosphabarrelene ligand is used in the platinum-catalyzed hydrosilylation of alkynes. High regioselectivities were achieved under mild conditions from an in situ formed catalyst at low catalyst loadings. Furthermore, a rare 14-VE PtL2 complex was isolated, which equally proved to be a highly reactive catalyst precursor.

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