Journal
ORGANOMETALLICS
Volume 28, Issue 8, Pages 2360-2362Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900067f
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Funding
- CNRS (Centre National de la Recherche Scientifique)
- Ecole Polytechnique
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A bulky phosphabarrelene ligand is used in the platinum-catalyzed hydrosilylation of alkynes. High regioselectivities were achieved under mild conditions from an in situ formed catalyst at low catalyst loadings. Furthermore, a rare 14-VE PtL2 complex was isolated, which equally proved to be a highly reactive catalyst precursor.
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