Journal
ORGANOMETALLICS
Volume 28, Issue 17, Pages 4899-4901Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om900267w
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- BP through the MC2 program
- G.S.C.
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In aqueous solution, [Pt-II(glycinato)Cl-2](-) catalyzes oxidation by [(PtCl6)-Cl-IV](2-) of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [(PtCln)-Cl-II(H2O)(4-n)](2-n) as the catalyst.
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