Journal
ORGANOMETALLICS
Volume 27, Issue 4, Pages 789-792Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om700926d
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The reaction of a macrocyclic Rh(I) complex having hemilabile PO ligands with Cl- results in Rh-O bond breakage and yields a Cl-bridged tetranuclear Rh(I) complex, which was characterized by a single-crystal X-ray diffraction study. Reactivity of the complex with CO and halide abstracting agents is described.
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