Journal
ORGANIC PROCESS RESEARCH & DEVELOPMENT
Volume 18, Issue 10, Pages 1245-1252Publisher
AMER CHEMICAL SOC
DOI: 10.1021/op500173q
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- EPSRC
- AstraZeneca
- Deutsche Forschungsgemeinschaft
- Royal Society Wolfson Research Merit Award
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The deprotonation of N'-arylurea derivatives of cyclohexenamines by alkyllithiums leads to migration of the N'-aryl substituent from N' to the allylic position alpha to N via rearrangement of a urea-stabilised allyllithium intermediate. The product ureas may be solvolysed to reveal 1-arylcydohexenamines.
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