Journal
ORGANIC LETTERS
Volume 20, Issue 17, Pages 5402-5405Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b02310
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21572051, 21602057]
- Opening Fund of Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education of China), Hunan Normal University [KLCBTCMR201707, KLCBTCMR201708]
Ask authors/readers for more resources
A novel tandem intermolecular decarboxylative coupling reaction of o-bromobenzoic acids and aryl iodides has been developed. The method affords a range of unsymmetrically triphenylenes and displays unique regioselectivity and broad substrate scope. Mechanistically, palladium/norbornene-catalyzed C-H activation and subsequent double decarboxylative coupling reactions were involved. Moreover, the triphenylenes can also be synthesized from 2-iodobiphenyls and o-bromobenzoic acids under norbornene-free conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available