4.8 Article

Catalytic Asymmetric Intermolecular Bromoesterification of Unfunctionalized Olefins

Journal

ORGANIC LETTERS
Volume 16, Issue 14, Pages 3728-3731

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol501542r

Keywords

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Funding

  1. National Basic Research Program of China (973 program) [2011CB808600]
  2. National Natural Science Foundation of China [21172221]
  3. Chinese Academy of Sciences

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An asymmetric intermolecular bromoesterification of unfunctionalized olefins catalyzed by (DHQD)(2)PHAL is described. Optically active bromoesters can be obtained with up to 92% ee.

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