Journal
ORGANIC LETTERS
Volume 16, Issue 22, Pages 5862-5865Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol502749b
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Funding
- 973 Program [2011CB808601]
- 863 Program [2013AA031901]
- National NSF of China [21372164, 21172155, 21025205, 21272160, 21321061, 21432005, J1103315]
- Sichuan Provincial Foundation [2012JQ0002]
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An efficient protocol for the synthesis of (hetero)aryl carboxylic esters has been achieved by Pd-catalyzed CH carbonylation of (hetero)arenes with aryl formates. A relatively wide range of functional groups can be tolerated in this transformation, and the corresponding esters are obtained in good yields. On this basis, an intramolecular oxidative CH/CH coupling has been developed to prepare indolo[3,2-c]coumarins.
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