Journal
ORGANIC LETTERS
Volume 17, Issue 2, Pages 374-377Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5035386
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- CAS
- National Natural Science Foundation [21272234, 21202166]
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The differentiation of two nucleophilic amide groups in malonamides through a copper-catalyzed enantioselective intramolecular aryl C-N coupling reaction is demonstrated based on an asymmetric desymmetrization strategy. Such a method afforded enantioenriched 2-oxo-1,2,3,4-tetrahydroquinoline-3-carboxamides in high yields and moderate to good enantioselectivity.
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