Journal
ORGANIC LETTERS
Volume 16, Issue 5, Pages 1446-1449Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5002413
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Funding
- National Science Foundation [CHE-1152488]
- National Institutes of Health [NIGMS 104349]
- Region Rhone-Alpes
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1152488] Funding Source: National Science Foundation
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A new synthetic route to access diarylmethyl phosphonates is presented. The transformation enables the introduction of aromatic groups on benzylic phosphonates via a deprotonative cross-coupling process (DCCP). The Pd(OAc)(2)/CataCXium A-based catalyst afforded a reaction between benzyl diisopropyl phosphonate derivatives and aryl bromides in good to excellent isolated yields (64-92%).
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