Journal
ORGANIC LETTERS
Volume 16, Issue 6, Pages 1574-1577Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol500105d
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Funding
- National Institutes of Health [GM081267]
- University of Minnesota through the Vince and McKnight Endowed Chairs
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An oxidative boron Heck reaction of cyclic enaminones with arylboronic acids is reported. This protocol provides a regioselective arylation it the C6 position of cyclic enaminones. When an N-carbamylated cyclic enaminone was employed, a switch to a conjugate addition reaction occurred in the presence of acid.
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