Journal
ORGANIC LETTERS
Volume 15, Issue 19, Pages 5016-5019Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402351c
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Funding
- National Basic Research Program of China (973 Program) [2010CB833300]
- NSFC [20902099, 21172238]
- SIOC
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Highly stereoselective addition of diarylphosphines to alpha,beta-unsaturated sulfonic esters catalyzed through a PCP pincer-Pd complex is developed to synthesize chiral phosphine sulfonic esters with excellent enantioselectivity (up to 99.5% ee). The transformation of the chiral adduct into a useful palladium phosphine sulfonate complex is also demonstrated.
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