Journal
ORGANIC LETTERS
Volume 16, Issue 1, Pages 314-317Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol403346x
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Funding
- XJTU
- National Natural Science Foundation of China [21202128]
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An efficient aminocyanation by the direct addition of aryl cyanamides to arynes is described, enabling incorporation of highly useful amino and cyano groups synchronously via cleavage of inert N-CN bonds, affording synthetically useful 1,2-bifunctional aminobenzonitriles. The postsynthetic functionalization of the aminocyanation products allows diverse formation of synthetically important derivatives such as drug molecule Ponstan and fused heterocycles.
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