Journal
ORGANIC LETTERS
Volume 15, Issue 22, Pages 5722-5725Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402748u
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Funding
- National Natural Science Foundation of China [21172143, 21232004]
- Shanghai Jiao Tong University (SJTU)
- Nippon Chemical Industrial Co., Ltd
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The insertion of arynes into arylphosphoryl amide bonds to synchronously construct C-P and C-N bonds is described. Arynes generated in situ from o-triflate arylsilanes under fluoride-promoted conditions insert into relatively inert P-N bonds, producing o-amine-substituted arylphosphine oxides. This process provides a simple pathway for the preparation of precursors for a number of bidentate aminophosphine ligands.
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