Journal
ORGANIC LETTERS
Volume 15, Issue 18, Pages 4798-4801Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol402172x
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Funding
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- NSERC CGS program
- Alberta Innovates
- University of Calgary for support through the Program for Undergrad Research Experience (PURE)
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Three isomeric donor-acceptor (DA) chromophores based on pyrene were synthesized to study the effects of substitution pattern on intramolecular charge-transfer absorption through pyrene. These chromophores are nonfluorescent and absorb light in the long-wavelength region approaching 700 nm, making them promising light-harvesters. Their optical properties depend greatly on the substitution pattern of the donor, but their electrochemical properties are relatively unaffected.
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