Journal
ORGANIC LETTERS
Volume 15, Issue 22, Pages 5694-5697Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol4026974
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- Italian MIUR [PRIN 20109Z2X RJ_006]
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The first example of an oriented handcuff rotaxane has been obtained by through-the-annulus threading of a double-calix[6]arene system with a bis-ammonium axle. The relative orientation of the two calix-wheels can be predefined by exploiting the endo-alkyl rule which controls the directionality of the threading of alkylbenzylammonium axles with calixarene macrocycles.
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