Journal
ORGANIC LETTERS
Volume 15, Issue 8, Pages 1886-1889Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol400539h
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Funding
- Leverhulme Trust [F/00 276/O]
- EPSRC
- Nuffield Undergraduate Bursary
- Erasmus
- Engineering and Physical Sciences Research Council [1141118] Funding Source: researchfish
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A simple change of solvent allows controlled and efficient switching between oxidative Heck and conjugate addition reactions on cyclic Michael acceptor substrates, catalyzed by a cationic Pd(II) catalyst system. Both reactions are ligand- and base-free and tolerant of air and moisture, and the controlled switching sheds light on some of the factors which favor one reaction over the other.
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