Journal
ORGANIC LETTERS
Volume 14, Issue 4, Pages 1086-1089Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol203486p
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Funding
- Academy of Finland [217221, 217224, 139046]
- Department of Chemistry, University of Jyvaskyla (JYU)
- JYU [AF-212588]
- Academy of Finland (AKA) [139046, 139046, 217221, 217224, 217224, 217221] Funding Source: Academy of Finland (AKA)
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Enantioselective iminium-catalyzed reactions with acrolein and methacrolein are rare. A catalytic enantioselective Mukaiyama-Michael reaction that readily accepts acrolein or methacrolein as substrates, affording the products in good yields and 91-97% ee, is presented. As an application of the methodology, an enantioselective route to the key C17-C28 segment of the pectenotoxin using the Mukaiyama-Michael reaction as the key step is described.
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