Journal
ORGANIC LETTERS
Volume 14, Issue 6, Pages 1416-1419Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3001552
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Funding
- NIGMS [GM-64451]
- NSF [DBI-0619576]
- AstraZeneca
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Two highly efficient and convenient methods for the synthesis of functionalized and substituted allylic boronates are described. In one procedure, readily available allylic acetates are converted to allylic boronates catalyzed by Ni/PCy3 or Ni/PPh3 complexes with high levels of stereoselectivity and in good yields. Alternatively, the borylation can be accomplished with commercially available Pd catalysts [e.g., Pd-2(dba)(3), PdCl2, Pd/C], starting with easily accessed allylic halides.
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