Journal
ORGANIC LETTERS
Volume 14, Issue 16, Pages 4250-4253Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3019665
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Funding
- National Natural Science Foundation of China [21172045, 20902011]
- Shanghai Shuguang Program [11SG04]
- Changjiang Scholars and Innovative Research Team in University [IRT1117]
- Shanghai Leading Academic Discipline Project [B108]
- Department of Chemistry, Fudan University
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Robust acenaphthoimidazolylidene palladium complexes have been demonstrated as highly efficient and general catalysts for the sterically hindered Suzuki-Miyaura cross-coupling reactions in excellent yields even with low catalyst loadings under mild reaction conditions. The high catalytic activity of these complexes highlights that, besides the flexible steric bulky concept, sigma-donor properties of the NHC ligands are also crucial to accelerate the transformations.
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