Journal
ORGANIC LETTERS
Volume 14, Issue 24, Pages 6366-6369Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3031704
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Funding
- EU STREP [PHOTOLYSIS- LSHM-CT-2007-037765]
- FRM [FDT20091217593]
- [ANR-2010-BLAN-1436-01]
- Medical Research Council [U117512659] Funding Source: researchfish
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The systematic SAR study of a caging group showed a strong influence of the position of the donor dimethylamino group on the efficiency of photolysis of the DMAQ (2-hydroxymethylene-(N,N-dimethylamino)quinoline) caged acetate under one-photon near-UV or two-photon near-IR excitation. Photorelease of L-glutamate by the most efficient 8-DMAQ derivative strongly and efficiently activated glutamate receptors, generating large, fast rising responses similar to those elicited by glutamate photoreleased from the widely used MNI-caged glutamate.
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