Journal
ORGANIC LETTERS
Volume 14, Issue 18, Pages 4970-4973Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol302379a
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- University of British Columbia
- Canada Research Chair Program
- NSERC
- CIHR
- CFI
- BCKDF
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The Ti(IV)-catalyzed Ugi condensation of alpha-amino acids with electron-rich aromatic aldehydes performs adequately even with sterically demanding alpha-amino carboxylate salts. The reaction occurs diastereoselectively, in some cases with virtually complete diastereoselectivity. A stereochemical rationale for the reaction is proposed.
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