Journal
ORGANIC LETTERS
Volume 14, Issue 3, Pages 696-699Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol203158p
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Funding
- Royal Society
- BP Endowment
- Alexander von Humboldt award
- Fonds der Chemischen Industrie
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A total synthesis of millingtonine A, a diglycosylated alkaloid, has been accomplished. Millingtonine A possesses a unique racemic tricyclic core structure not known from any other natural or synthetic source until now. The synthesis features a key bond-forming radical Ueno-Stork cyclization to form the heterocyclic core.
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