Journal
ORGANIC LETTERS
Volume 14, Issue 10, Pages 2582-2585Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3008815
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Funding
- NSF [CHE-0848847]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [848847] Funding Source: National Science Foundation
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An asymmetric synthesis of two new diastereomeric gamma-amino acids is described. Both molecules contain a cyclohexyl ring to limit conformational flexibility about the C-alpha-C-beta bond; they differ in having cis vs trans stereochemistry on the ring. Residues derived from the cis gamma isomer are shown to support helical secondary structures in alpha/gamma-peptide oligomers.
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