Journal
ORGANIC LETTERS
Volume 14, Issue 12, Pages 3096-3099Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol301184j
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Funding
- NSFC-Guangdong Province [U0932004]
- National Natural Science Foundation of China [20902038]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0965]
- Research Team of Natural Science Foundation of Guangdong Province [8351063201000003]
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Two new Securinega alkaloids, virosaines A (1) and B (2), were isolated from the twigs and leaves of Flueggea virosa. The structures and absolute configurations were elucidated by means of NMR, X-ray diffraction, and CD analyses. Compounds 1 and 2 represent the first examples of Securinega alkaloids bearing a 7-oxa-1-azabicyclo[3.2.1]octane ring system, whose plausible biogenetic pathways were also proposed.
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