Journal
ORGANIC LETTERS
Volume 15, Issue 1, Pages 14-17Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3028658
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- CSIR, New Delhi
- Department of Science and Technology, New Delhi
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A facile synthesis of natural and unnatural arylnaphthalenes has been demonstrated via the unprecedented palladium-promoted [2 + 2 + 2] cocyclization of arynes and unsymmetrical conjugated dienes using the N-heterocyclic carbene as a ligand. The unsymmetrical dienes used herein are actually alpha-coupled acrylate - cinnamate combinations bearing two beta-positive carbons and follow the key [2 + 2 + 2] cocyclization pathway.
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