Journal
ORGANIC LETTERS
Volume 14, Issue 23, Pages 5836-5839Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol3026582
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- BYU Department of Chemistry and Biochemistry
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Density functional theory was used to model glycinate enolate binding and enantiomeric allylation transition states mediated by the cinchonidinium phase-transfer catalyst 2. Transition states show oxy-anion-ammonium interactions in contrast to pi-face interactions in the ground states. The details of stereoselectivity are described within the quaternary ammonium-tetrahedron face model.
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