Journal
ORGANIC LETTERS
Volume 13, Issue 19, Pages 5240-5243Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202124b
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- Grants-in-Aid for Scientific Research [22689004, 22659020] Funding Source: KAKEN
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The first total synthesis of pacidamycin D, which is expected to be a good candidate as an antibacterial agent against P. aeruginosa, is described. The key elements of our approach feature an efficient and stereocontrolled construction of the Z-oxyvinyl iodide and copper-catalyzed cross-coupling with the tetrapeptide carboxamide.
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