Journal
ORGANIC LETTERS
Volume 13, Issue 19, Pages 5318-5321Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202181g
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A structure revision for the recently isolated fungal meroterpenoids, cytosporolides A-C, is suggested based on biosynthetic speculation and reinterpretation of existing spectroscopic data. The structure revision is supported by a biomimetic synthetic study, featuring a [4 + 2] cycloaddition reaction between a presumed o-quinone methide intermediate and beta-caryophyllene.
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