4.8 Article

A Concise Approach to the Dalesconol Skeleton

Journal

ORGANIC LETTERS
Volume 13, Issue 17, Pages 4494-4497

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol2015847

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Funding

  1. National Basic Research Program of China (973 program) [2011CB808600]
  2. Chinese Academy of Sciences

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A rapid approach to the skeleton of dalesconol A and B, unprecedented immunosuppressants, has been achieved through a convergent strategy featuring a carbocation-mediated dearomatization-cyclization and a following one-pot consecutive operation.

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