Journal
ORGANIC LETTERS
Volume 13, Issue 20, Pages 5540-5543Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202177k
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Funding
- National Research Foundation of Korea
- Korean Government [2011-0003169]
- Inha University [Inha-2011]
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The beta-diketiminatophosphane Pd complex acted as a powerful catalyst for the Heck coupling of aryl chlorides with alkenes. Various aryl and heteroaryl chlorides were coupled efficiently under relatively mild conditions. Furthermore, this catalytic system also proved to be highly active in the Buchwald-Hartwig coupling of deactivated and sterically hindered aryl chlorides at room temperature.
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