Journal
ORGANIC LETTERS
Volume 13, Issue 24, Pages 6520-6523Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202808n
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- Department of Science and Technology, India
- Council of Scientific and Industrial Research, New Delhi
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Organocatalytic conjugate addition of thiols to alpha-substituted N-acryloyloxazolidin-2-ones followed by asymmetric protonation has been studied in the presence of cinchona alkaloid derived thioureas. Both of the enantiomers are accessible with the same level of enantioselectivity using pseudoenantiomeric quinine/quinidine derived catalysts. The addition/protonation products have been converted to useful biologically active molecules.
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