Journal
ORGANIC LETTERS
Volume 13, Issue 17, Pages 4479-4481Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2016252
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Funding
- CNRS
- Ministere de l'Education Nationale et de la Recherche, France
- French Embassy in Germany
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A general and convenient protocol for the electrophilic borylation of aryl Grignard reagents prepared from arylbromides by direct insertion of magnesium in the presence of LiCl or by Mg/Br exchange with (PrMgCl)-Pr-l center dot LiCl has been developed. Various aryl boronic acids were synthesized in a straightforward manner in excellent yields at 0 degrees C.
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