Journal
ORGANIC LETTERS
Volume 13, Issue 18, Pages 4914-4917Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2019955
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Funding
- NCET [NCET-10-0371]
- FRFCU [2009ZM0262]
- NSFC [21072063]
- RFDP [20100172120020]
- GNSF [10351064101000000]
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C-Acylimines 1 undergo intermolecular amidation with amides 2 to produce monoacyl gem-diamino acid derivatives 3 upon treatment with Cu(OTf)(2) (20 mol %)/PPh(3) (20 mol %) under mild conditions. This method provides an efficient access to gem-diamino acid equivalents with good to excellent yields.
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