Journal
ORGANIC LETTERS
Volume 14, Issue 1, Pages 102-105Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202848a
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Funding
- National Science Foundation (NSF) [CHE 0956784]
- Dow Chemical Co.
- China Scholarship Council
- Northwest A F University
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0956784] Funding Source: National Science Foundation
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A highly regloselective isomerization-hydroaminomethylation of internal olefins has been developed. A 95.3% amine selectivity and 36.2 n/i ratio were obtained for 2-octene with a Tetrabi ligand and Rh(acac)(CO)(2), and a TON of linear amine was achieved of 6837 with a 39.1 n/i ratio of amine. The m-CF3-Ph substituted ligand was the best of the applied Tetrabi-type phosphorus ligands for different internal olefins, as up to a 99.2% amine selectivity and 95.6 n/i ratio were obtained for 2-pentene.
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