Journal
ORGANIC LETTERS
Volume 13, Issue 4, Pages 796-799Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol103064f
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Funding
- Duke University
- NCBC [2008-IDG-1010]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0923097] Funding Source: National Science Foundation
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Both 2,6-cis- and 2,6-trans-piperidines were prepared from common substrates through organocatalytic aza-Michael reactions promoted by the gem-disubstituent effect in conjunction with dithiane coupling reactions. The organocatalytic aza-Michael reaction enabled a facile synthesis of (+)-myrtine and (-)-epimyrtine from a common substrate.
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