Journal
ORGANIC LETTERS
Volume 12, Issue 15, Pages 3324-3327Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100929z
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Funding
- UC Davis Academic Senate Committee
- NIH/NIAID [R56AI80931-01]
- United States Department of Education
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An efficient, convergent synthesis of totarol by a diastereoselective epoxide/alkene/arene bicyclization is described. The reported synthesis enables the preparation of related diterpenes totaradiol and totarolone as well as previously unavailable derivatives that exhibit comparable Inhibition of the bacterial cell division protein FtsZ.
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