Journal
ORGANIC LETTERS
Volume 12, Issue 24, Pages 5736-5739Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102554a
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Funding
- MEXT, Japan
- NOASTEC
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Stepwise application of the Pd-catalyzed S(N)2' reaction and the desilylative S(E)2' reaction to the ambivalent 2-bromo-1-silyl-1,3-dienes provides a novel route to the highly enantioselective construction of tertiary and quaternary propargylic stereogenic centers via axially chiral allenylsilanes.
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