Journal
ORGANIC LETTERS
Volume 12, Issue 21, Pages 4788-4791Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1019376
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- COE Foundation of Kyoto Pharmaceutical University
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Gold(I)-catalyzed asymmetric cyclization of 1,3-dihydroxymethyl-2-alkynylbenzene chromium complexes gave planar chiral isochromene chromium complexes with high enantioselectivity. Enantiomeric excess of the cyclization products was largely affected by a combination of axially chiral diphosphine(AuCl)(2) precatalysts and silver salts. A system of segphos(AuCl)(2) with AgBF4 resulted in the formation of the corresponding antipode.
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