Journal
ORGANIC LETTERS
Volume 12, Issue 17, Pages 3950-3953Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1017189
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Funding
- Swiss National Science Foundation [NF5/2-7723408]
- ETH
- Novartis
- Roche Research Foundation
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The total synthesis of Microcin SF608 is reported. Access to the octahydroindole core structure of Microcin SF608 relies on the TMSOTf/NEt3-mediated opening of an oxabicyclic ring system. Additional highlights of the synthetic strategy that is reported include a highly regioselective epoxide reduction and photolytic excision of a 3 alcohol.
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