Journal
ORGANIC LETTERS
Volume 11, Issue 13, Pages 2852-2854Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9010739
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- Swedish Research Council
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Palladium pincer complexes directly catalyze the redox coupling reactions of functionalized alkenes and iodonium salts. The catalytic process, which Is suitable for mild catalytic functionalization of allylic acetates and electron-rich alkenes, probably occurs through Pd(IV) intermediates. Due to the strong metal-ligand interactions, the oxidation of phosphine and amine ligands of the pincer complexes can be avoided in the presented reactions.
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