Journal
ORGANIC LETTERS
Volume 11, Issue 23, Pages 5478-5481Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902307m
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- Natural Sciences and Engineering Research Council of Canada
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(E)-1,2-Dichlorovinyl ethers and amides are easily accessible from trichloroethylene via nucleophilic addition across in situ synthesized dichloroacetylene. A one-pot, sequential Suzuki-Miyaura coupling/intramolecular direct arylation between dichlorovinyl ethers and organoboronic acids provides easy access to a variety of benzofurans in only two steps from inexpensive commercially available compounds. The method is extendable to the preparation of indoles from the analogous dichlorovinyl amides.
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